I would start on the "Interactive CAFE Menu" (it's listed under the green CAFE tab on the main page). Here's the link to that resource: https://www.thedailycafe.com/cafe/cafe-menus/interactive-cafe-menu
When you click on any strategy in the menu, it will take you to a map of all the resources available on the website connected with that. For example, if you wanted to work on the Strategy "Use prior knowledge to connect with the text", when you click that on the menu, this is what you'll see:
https://www.thedailycafe.com/strategies/comprehension/use-prior-knowledge-to-connect-with-text . This place lists all the videos, forms and suggested lessons on the site. If I were you, I'd print out the "Ready Reference Forms", the Parent Pipeline, the "I Can" bookmark and put them in a folder or notebook. You could do this with all the strategies ahead of time to create your own materials in a way that works for you. Yes it will take a while, but then you have it :).
Another alternative is to decide which strategies you want to introduce your students first, and start with those. Then, print out the new ones as you have need.
If you had the "physical book" for CAFE, it comes with a CD that has printable versions of the Ready Readiness forms and forms for the Pensieve (which you've seen in the appendix on your Kindle book), but you would need to get the other forms from the website.
The Sisters intend for the website to be a resource that is constantly updated, so there are many resources that have been added since the book was published. Don't get discouraged, though--once you get used to using the site, you'll see how it can be a great resource for you.
Again, I'd start with the Interactive CAFE Menu. You also can bookmark places you want to keep at your fingertips. The "Search" tab is also very helpful if you have a specific topic you want to read about.
And, of course, using the Discussion Board as a way to talk with teachers who are familiar with the site can help direct you to find what you need.
It really is exciting to get involved in Daily 5 and CAFE, and you'll see the pay-off with your students in a big way.